An impure semiconductor, which is formed by doping a pure semiconductor is called as an extrinsic semiconductor. There are two types of extrinsic semiconductors depending upon the type of impurity added. They are N-type extrinsic semiconductor and P-Type extrinsic semiconductor.

N-Type Extrinsic Semiconductor

A small amount of pentavalent impurity is added to a pure semiconductor to result in Ntype extrinsic semiconductor. The added impurity has 5 valence electrons.

For example, if Arsenic atom is added to the germanium atom, four of the valence electrons get attached with the Ge atoms while one electron remains as a free electron. This is as shown in the following figure.

All of these free electrons constitute electron current. Hence, the impurity when added to pure semiconductor, provides electrons for conduction.

·        In N-type extrinsic semiconductor, as the conduction takes place through electrons, the electrons are majority carriers and the holes are minority carriers.

·        As there is no addition of positive or negative charges, the electrons are electrically neutral.

·        When an electric field is applied to an N-type semiconductor, to which a pentavalent impurity is added, the free electrons travel towards positive electrode. This is called as negative or N-type conductivity.

P-Type Extrinsic Semiconductor

A small amount of trivalent impurity is added to a pure semiconductor to result in P-type extrinsic semiconductor. The added impurity has 3 valence electrons. For example, if Boron atom is added to the germanium atom, three of the valence electrons get attached with the Ge atoms, to form three covalent bonds. But, one more electron in germanium remains without forming any bond. As there is no electron in boron remaining to form a covalent bond, the space is treated as a hole. This is as shown in the following figure.

The boron impurity when added in a small amount, provides a number of holes which helps in the conduction. All of these holes constitute hole current.

·        In P-type extrinsic semiconductor, as the conduction takes place through holes, the holes are majority carriers while the electrons are minority carriers.

·        The impurity added here provides holes which are called as acceptors, because they accept electrons from the germanium atoms.

·        As the number of mobile holes remains equal to the number of acceptors, the Ptype semiconductor remains electrically neutral.

·        When an electric field is applied to a P-type semiconductor, to which a trivalent impurity is added, the holes travel towards negative electrode, but with a slow pace than electrons. This is called as P-type conductivity.

·        In this P-type conductivity, the valence electrons move from one covalent bond to another, unlike N-type.

Why Silicon is Preferred in Semiconductors?

Among the semiconductor materials like germanium and silicon, the extensively used material for manufacturing various electronic components is Silicon (Si). Silicon is preferred over germanium for many reasons such as −

·        The energy band gap is 0.7ev, whereas it is 0.2ev for germanium.

·        The thermal pair generation is smaller.

·        The formation of SiO2 layer is easy for silicon, which helps in the manufacture of many components along with integration technology.

·        Si is easily found in nature than Ge.

·        Noise is less in components made up of Si than in Ge.

Hence, Silicon is used in the manufacture of many electronic components, which are used to make different circuits for various purposes. These components have individual properties and particular uses.

The main electronic components include — Resistors, variable resistors, Capacitors, variable capacitors, Inductors, diodes, Tunnel diodes, Varactor diodes, Transistors, BJTs, UJTs, FETs, MOSFETs, LDR, LED, Solar cells, Thermistor, Varistor, Transformer, switches, relays, etc.